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(9分)(1)1 mol气态钠离子和1 mol气态氯离子结合生成1 mol氯化钠晶体释放出的热能为氯化钠晶体的晶格能。 ①下列热化学方程式中,能直接表示出氯化钠晶体晶格能的是____________。 A.Na + (g)+Cl - (g)―→NaCl(s);△Q B.Na(s)+Cl 2 (g)―→NaCl(s);△Q 1 C.Na(s)―→Na(g);△Q 2 D.Na(g)-e - ―→Na + (g);△Q 3 E.Cl 2 (g)―→Cl(g);△Q 4 F.Cl(g)+e - ―→Cl - (g);△Q 5 ②写出△Q 1 与△Q、△Q 2 、△Q 3 、△Q 4 、△Q 5 之间的关系式________________________________________________________________________ (2)可逆反应:aA(g)+bB(g) cC(g)+dD(g),取a mol A和b mol B置于V L密闭容器中,2 min后,测得容器中A的浓度为x mol·L -1 ,以物质C的浓度变化来表示这段时间内反应的平均速率应为__________ __。
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