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准确称取 Na 2 CO 3 试样 0.1450g, 以蒸馏水溶解后以甲基橙为指示剂,以浓度为 0.1066mol/L 的 HCl 滴定,滴定中用去 HCl 溶液 24.50mL 。已知 Na 2 CO 3 的摩尔质量为 106.0g/mol. 计算该 Na 2 CO 3 的含量。 2. 精密称取阿司匹林试样0.4227g,加入20ml的中性乙醇溶解后,加2d酚酞指示剂,用0.1010 mol/L的NaOH标准溶液滴定,终点时消耗22.68ml。1ml的0.1000mol/L NaOH标准溶液相当于18.06mg的阿司匹林。 试计算试样中阿司匹林的含量。 3. 用邻苯二甲酸氢钾基准物标定氢氧化钠,平行滴定三份。称取的邻苯二甲酸氢钾质量及消耗的氢氧化钠滴定液的体积数据如下: 第一份: m 1 =0.5510g V 1 =26.62ml 第二份: m 2 =0.5611g V 2 =27.00ml 第三份: m 3 =0.5233g V 3 =25.20ml 已知:邻苯二甲酸氢钾的摩尔质量为 204.2g/mol 。 (1) 计算氢氧化钠溶液的平均浓度。 (2) 计算分析结果的相对平均偏差。 4. 欲配制0. 1000moL/LNa 2 CO 3 溶液500. 0ml,问取基准Na 2 CO 3 多少克?并说出是在量杯还是容量瓶中配制? Na 2 CO 3 的摩尔质量为105.9g/ml) 5.精密称取CaCO 3 试样0.1132g,准确加入0.1078mol/L HCI滴定液25.00ml,剩余的HCI用0.1037mol/L 氢氧化钠的滴定液滴定,消耗氢氧化钠滴定液11.45ml, 求试样CaCO 3 的含量百分数。请回答此方法是属于哪种滴定方式? (CaCO 3 的摩尔质量为100.09gmol)
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