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【简答题】
在pH=5.0时,以二甲酚橙(XO)为指示剂,以0.020mol·L -1 EDTA滴定浓度均为0.020mol·L -1 的Zn 2+ 和Cd 2+ 混合溶液中的Zn 2+ ,加入过量KI,使终点时,[I - ]=1mol·L -1 。问:①能否用XO作指示剂滴定Zn 2+ ?Cd 2+ 是否产生干扰?②终点误差为多少?(lgK CaY =16.46;pH=5.0时,pZn ep(XO) =4.8,lgα Y(H) =6.45;Cd 2+ 与I - 络合物的lgβ 1 ~lgβ 4 分别为2.10、3.43、4.49、5.41;lgK ZnY =16.5)
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