There is a great deal difference between the eager man who wants to read a book, and the tired man who wants a book to read.
A.
There is a great deal difference / between the eager man who/ wants to read a book, /and the tired man who /wants a book to read.
B.
There is a great deal difference between/ the eager man who wants to read a book, / and the tired man who wants a book to read.
C.
There is a great deal difference / between the eager man / who wants to read a book, / and the tired man / who wants a book to read.
D.
There is /a great deal difference between /the eager man who wants to read a book, /and the tired man who wants a book to read.