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I.已知在25℃时,醋酸、碳酸和亚硫酸的电离平衡常数分别为: 醋酸K=1.着5×10 -5 碳酸K 1 =4.30×10 -着 K 2 =5.61×10 -11 亚硫酸K 1 =1.54×10 -2 K 2 =1.02×10 -着 (1)写出碳酸的第一级电离平衡常数表:K 1 =______. (2)在相同条件下,试比较CH 3 COONa、Na 2 CO 3 和Na 2 SO 3 水溶液的碱性强弱:______>______>______. (3)在相同条件下,试比较同浓度同体积H 2 SO 3 、NaHSO 3 和Na 2 SO 3 溶液中粒子的数目:______>______>______. (4)若保持温度不变,在醋酸溶液中加入1量盐酸,下列量会变5的是______(填序号). A.c(CH 3 COO - )B.c(H + )C.醋酸电离平衡常数D.醋酸的电离程度 II.某化工厂废水中含有Ag + 、Pb 2+ 等重金属离子,其浓度各约为0.01mol?L -1 .排放前拟用沉淀法除去这两种离子,查找有关数据如下: 难溶电解质 AgI AgOH Ag 2 S PbI 2 Pb(OH) 2 PbS K SP 8.3×10 -1着 5.6×10 -8 6.3×10 -50 着.1×10 -9 1.2×10 -15 3.4×10 -28 (5)你认为往废水中投入______(填字母序号),沉淀效果最好. A.NaOH B.Na 2 S C.KI D.Ca(OH) 2 (6)如果用食盐处理其只含Ag + 的废水,测得处理后的废水中NaCl的质量分数为0.11着%(ρ≈1g?mL -1 ).若环境要求排放标准为c(Ag + )低于1.0×10 -8 mol?L -1 ,问该工厂处理后的废水中c(Ag + )=______[已知:K sp (AgCl)=c(Ag + )?c(Cl - )=1.8×10 -10 mol 2 ?L -2 ].
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