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(5分)(1)物质形成分子间氢键和分子内氢键对物质性质的影响有显著差异。根据下表数据,形成分子间氢键的物质是___________ (填物质字母代号)。 代号 物质 结构 水中溶解度/g (25℃) 熔点/℃ 沸点/℃ A 对—硝基苯酚 1.7 114 295 B 邻—硝基苯酚 0.2 45 100 (2)由C、H、O、S中元素构成甲、乙、丙三种分子,所含原子的数目依次为3、4、8,都含有18个电子。甲和乙的主要物理性质比较如下: 熔点/K 沸点/K 标准状况时在水中的溶解度 甲 187 202 2.6 乙 272 423 以任意比互溶 ①1 mol乙分子含有 个σ键; ②丙分子的中心原子采取 杂化轨道; ③甲和乙的相对分子质量基本相同,造成上述物理性质差异的主要原因是 (结合具体物质解释)。
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